Thermal Analyzers

What is the processing temperature of this resin?

Understanding the temperatures at which polymers soften and melt is a fundamental material property relevant to polymer processing. As one of the first steps in extrusion, injection molding and film blow molding processes, resin pellets are routinely heated past the melting point; for thermoforming and blow molding, the resin is heated above its glass transition temperature to soften it, but without completely melting it. This transformation from a solid resin pellet (lower energy state) to a softened or completely melted pellet (higher energy state) requires the input of energy and can be measured using Differential Scanning Calorimetry (DSC).

In a DSC test, the heat flow of the sample is monitored as the temperature is increased at a constant rate. Thermal transitions such as melting and glass transition show up as endothermic events, where the material absorbs heat as it moves into the higher energy state. The results also reveal information about the polymer morphology, with clear differences between amorphous and semi-crystalline states. During a DSC test’s first heat cycle, amorphous materials display a broad glass transition without melting, while semi-crystalline polymers have a sharp and well-defined melting peak. Since the melting and glass transition temperatures are unique to each polymer, this information can be used to quickly evaluate the quality of the incoming feedstock prior to processing.

Answer the following questions with results from your DSC:

• Feedstock evaluation: Is this a neat polymer, or is it a blend? Can vendor A’s resin be replaced with lower cost resin from vendor B?
• Processing: How much thermal energy is needed to completely melt the resin pellets?
• After processing: Is there a thermal history after processing vs. as-received? (1st vs. 2nd heat)
• End-of-life recycling: Does this batch of PCR (post-consumer resin) have significant contamination from other polymers?

How does this resin decompose?

Common thermoplastic processing techniques, like extrusion, injection molding and blow molding, require the resin to be heated above the melting point for easy processing. However, it is important to carefully control the processing temperatures to avoid resin degradation that can occur at elevated temperatures. For polymers, the onset of degradation can be identified as the temperature at which significant weight loss (typically >5%) starts to take place and can measured using a Thermogravimetric Analyzer (TGA).

During thermal analysis of polymers, TGA tests are routinely performed before DSC testing since the TGA results help establish the upper temperature limits for subsequent testing. Apart from identifying the degradation window for processing, TGA results also quantitatively reveal the composition of the major ingredients in the resin, such as the amount of base polymer, plasticizer, and filler present. The off-gas generated during a TGA experiment can be further analyzed to gain insights into the chemical identity of the decomposition products. This type of Evolved Gas Analysis (EGA) is especially powerful since it combines real-time TGA data with results from FTIR and GC-MS.

How stable is this resin during processing and end-use?

Stabilizers and other additives are often added to resins to prevent degradation from environmental effects encountered during processing and end-use conditions. These additives include antioxidants, oxygen scavengers, heat and UV light stabilizers, or flame retardants, to ensure the polymer’s intended properties are maintained during processing and the product’s lifetime. Stabilizers are inherently sacrificial and are gradually consumed when exposed to high temperature or UV light; once the stabilizer is completely exhausted, the polymer properties start to degrade rapidly.

The performance of stabilizers can be evaluated through Oxidative Induction Time (OIT) analysis on the DSC. In this isothermal test, the purge gas in the DSC is switched from Nitrogen to Oxygen, providing an environment where the stabilizer is consumed. At the onset of polymer degradation, the heat flow signal starts to increase and the time is noted as OIT.

Temperature ramps on the DSC can also be used to measure the Oxidative Onset Time (OOT), a related measure of polymer stability. Both OIT and OOT tests can also be performed using a high-pressure DSC, which reduces test time by accelerating stabilizer consumption.

Answer the following questions with OIT & OOT results from your DSC:

• Feedstock evaluation: Can this resin be processed as-is? Are antioxidants needed for additional stability?
• Failure Analysis: Did this part antioxidant at sufficient levels suitable for the end-use conditions?
• End-of-Life recycling: How much antioxidant is needed to stabilize and process this batch of PCR?

Related Application Notes:

• TS5:Determination of the Relative Oxidative Stability of Polyethylene Bottle Tops by Differential Scanning Calorimetry (DSC)
• TA121: Oxidative Stability of Polyethylene Terephthalate

How do process conditions affect the product’s crystallinity?

Semi-crystalline thermoplastics like Polyethylene (PE), Polypropylene (PP), and Polyethylene Terephthalate (PET) find extensive use across a range of applications, including in packaging materials. Semicrystalline polymer morphology is marked by the presence of locally ordered, crystalline regions interspersed between disorganized, amorphous regions. The presence of these crystalline domains within the structure confers desirable end-use properties including increased strength, wear performance, and chemical resistance. However, it is vital to carefully control the processing conditions to achieve the required levels of crystallinity in the product since high crystallinity can lead to brittle products, reduce optical clarity, or result in warpage and shrinkage defects.

Crystallization is the process of converting an amorphous, higher-energy structure into an organized, lower-energy, solid crystalline structure – this transition releases energy and can be accurately measured using Differential Scanning Calorimetry (DSC) as an exothermic peak. DSC tests are commonly performed in 3 distinct steps involving a heat-cool-heat cycle. The first heat cycle evaluates the material as received and imparts a uniform, well-defined thermal history to the materials.

Once melted, the cooling cycle of a DSC curve provides information about crystallization – the temperatures at which crystallization starts and ends, and a quick overview of crystallization kinetics. Additional insights into crystallization kinetics can be obtained through more detailed isothermal tests. The amount and speed of crystallization can be controlled through the deliberate addition of nucleating agents; however, crystallization rates can also be affected by dyes, colorants, or contaminants in recycled resins that can serve as nucleating agents. Since crystallinity has a direct impact on product performance, careful measurement and control of crystallinity is critical to avoid product failures in the end-use application.

Answer the following questions with results from your DSC:

• Processing: What cooling rates are needed to achieve the required crystallinity? Are nucleating agents needed?
• End-of-life: How can the crystallinity of products made with PCR be matched with those from virgin materials?

Related Application Notes:

• TA393:Comparison of Crystallization Behavior of Different Colored Parts Made from PP Using a Single DSC Experiment
• TA448: Semi-Crystalline Thermoplastic Analysis Using the Discovery X3 DSC
• TA444: Comparison of the Thermal Behavior of Different Types of Recycled PET for Advanced Honeycomb Structures

How does the product perform?

Understanding the product performance under final end-use application conditions helps guide product formulation, process optimization, and plays an important role in troubleshooting and failure analysis. For plastic products, the mechanical properties are closely tied to the end-use product performance and can be evaluated through a combination of different mechanical testing techniques that provide information on the material’s modulus. Depending on the type of deformation, additional information and insights can also be obtained.

• Monotonic testing: Unidirectional deformation to failure under an applied load – test materials under conditions of increasing load (e.g., Stress-strain curves
• Fatigue testing: Understand damage and failure from repeated loading – test materials and finished products under conditions of increasing cycling (e.g., S/N curves)
• Dynamic Mechanical Analysis (DMA): Study solid viscoelastic properties as a function of temperature and deformation frequency (e.g., Glass transition temperature (Tg), Time-Temperature Superposition (TTS))

DMA testing investigates the temperature dependance of a solid specimen’s mechanical properties under bending, compression, or tensile deformation. It provides quantitative information about the material’s viscoelastic properties through the Storage Modulus (E’), Loss Modulus (E”) and tan(δ) (damping factor). When polymeric specimens are heated, they undergo transitions that are reflected in these mechanical parameters. DMA is one of the most sensitive techniques available to measure glass transition and beta transition temperatures, since it picks up on subtle changes in local polymer mobility brought about by the increased temperature.

Answer the following questions with results from your DMA:

• Processing: Was this batch of resins blended uniformly to achieve miscibility?
• Product performance: Does this product have the right mechanical strength/ stiffness for the intended end-use environmental conditions (temperature, relative humidity)?
• End-of-life: Do products produced with recycle resin match the mechanical properties of those made with virgin resins?

Related Application Notes:

• RH100: Measurement of Glass Transition Temperatures by Dynamic Mechanical Analysis and Rheology